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PRINCIPLES & APPLICATIONS OF THERMOELECTRIC MODULES A thermoelectric cooling/heating module is a miniature solid state heat pump having either a cooling or a heating function. Its principle is a phenomenon called "Peltier Effect" discovered by Peltier in 1834. He discovered that when two metal wires of different materials were joined to form an electrical circuit and a direct electrical current was made to flow through the circuit, one junction became cold and the other junction became hot; when the current direction was reversed, the cold junction got hot while the hot junction got cold. Since then, there have been constant efforts to make use of this principle. Solid state heat pumps became commercially attractive only recently, however, when high performance semi-conductor materials had been developed by early 1960's and the manufacturing technologies of the thermoelectric modules using the materials well developed. The semi-conductor materials currently widely used for making the thermoelectric modules are bismuth telluride, a quaternary alloy of bismuth, tellurium, selenium, and antimony-doped and reprocessed to yield oriented polycrystalline semiconductors with an-isotropic thermoelectric properties. When low-voltage DC power is applied through the modules, heat will be moved from one side of the module to the other side. By reversing the polarity, the heat will be moved in the opposite direction. Thus, a thermoelectric module can either heat or cool. Many modules can be either connected in parallel, or in a series, in a single heat pump for generating a specific cooling or heating capacity. Cascading the modules thermally in series can increase the temperature differential. Each module can be also considered a special resistor.
Applications
A thermoelectric power generating module is a miniature power generator producing a DC power . Its principle is a pheonomenon called "Seebeck Effect" discovered by Seebeck in 1922. He discovered that when a temperature difference was applied to the two junctions of the Peltier circuit, a direct current voltage was generated in the circuit. Therefore, any cooling/heating modules can become also power generating modules. Since both Peltier and Seebeck Effects are irreversible phenomena, however, electric power generating as a result of the temperature difference is much smaller than the power input to obtain the same temperature difference. Modern thermoelectric power generating modules utilize still bismuth telluride up to themperature of about 250°C. Beyond 400°C, lead telluride are used. HTRD has been collaborating with the foremost manufacturers in the world including those in the former Soviet Union for supplying thermoelectric modules (HT-series) which are the best in quality and yet most reasonable in price.
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